Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp(2))-H Bonds by Carbene Insertion

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dc.contributor.authorConde Alcántara, Ana Isabel
dc.contributor.authorSabenya, Gerard
dc.contributor.authorRodríguez, Mònica
dc.contributor.authorPostils, Verònica
dc.contributor.authorLuis, Josep M.
dc.contributor.authorDíaz Requejo, María Mar
dc.contributor.authorCostas, Miquel
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2019-05-09T10:21:28Z
dc.date.available2019-05-09T10:21:28Z
dc.date.issued2016
dc.descriptionTítulo de la versión post-print: Introducing Fe and Mn as catalysts for the selective functionalization of Csp2-H bonds of arenes by carbene insertiones_ES
dc.description.abstractThe first examples of the direct functionalization of non-activated aryl sp(2) C-H bonds with ethyl diazoacetate (N2CHCO2Et) catalyzed by Mn- or Fe-based complexes in a completely selective manner are reported, with no formation of the frequently observed cycloheptatriene derivatives through competing Buchner reaction. The best catalysts are Fe-II or Mn-II complexes bearing the tetradentate pytacn ligand (pytacn = 1-(2-pyridylmethyl)-4,7-dimethyl-1,4,7-triazacyclononane). When using alkylbenzenes, the alkylic C(sp(3))-H bonds of the substituents remained unmodified, thus the reaction being also selective toward functionalization of sp(2) C-H bonds.es_ES
dc.description.centerCIQSO
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"
dc.description.sponsorshipSupport for this work was provided by the MINECO (CTQ2014-52769-C3-R-1, CTQ2014-62234-EXP, CTQ2015-70795-P, CTQ2014-54306-P, and CTQ2014-52525P), and the Junta de Andalucia (P10-FQM-06292). A.C. thanks Junta de Andalucia for a research contract. M.C. acknowledges an ICREA Academia Award, 2014 SGR 862 from Generalitat de Catalunya, and ERC-239910.
dc.identifier.citationConde, A., Sabenya, G., Rodríguez, M., Postils, V., Luis, J. M., Díaz-Requejo, M. M., … Pérez, P. J. (2016). Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2 )−H Bonds by Carbene Insertion. Angewandte Chemie International Edition, 55(22), 6530–6534. https://doi.org/10.1002/anie.201601750es_ES
dc.identifier.doi10.1002/anie.201601750
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773 electrónico
dc.identifier.urihttp://hdl.handle.net/10272/16239
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Andalucia [ P10-FQM-06292]info:eu-repo/grantAgreement/MINECO [CTQ2014-52769-C3-R-1, CTQ2014-62234-EXP, CTQ2015-70795-P, CTQ2014-54306-P, CTQ2014-52525P]
dc.relation.publisherversionhttps://doi.org/10.1002/anie.201601750es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherAreneses_ES
dc.subject.otherCarbenees_ES
dc.subject.otherC-H activationes_ES
dc.subject.otherIrones_ES
dc.subject.otherManganesees_ES
dc.titleIron and Manganese Catalysts for the Selective Functionalization of Arene C(sp(2))-H Bonds by Carbene Insertiones_ES
dc.titleIntroducing Fe and Mn as catalysts for the selective functionalization of Csp2-H bonds of arenes by carbene insertion
dc.typejournal articlees_ES
dspace.entity.typePublication
relation.isAuthorOfPublication53d21d81-0d89-4eb7-b5ec-344758de6744
relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscovery53d21d81-0d89-4eb7-b5ec-344758de6744

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