Revealing unbound β-diketiminate anions: structural dynamics from caesium complexes
| dc.contributor.author | Videa, Hellen | |
| dc.contributor.author | Martínez Martínez, Antonio Jesús | |
| dc.date.accessioned | 2023-09-27T10:54:21Z | |
| dc.date.available | 2023-09-27T10:54:21Z | |
| dc.date.issued | 2023-06-19 | |
| dc.description.abstract | This study reports the first structural elucidation of β-diketiminate anions (BDI−), known for strong coordination, in their unbound form within caesium complexes. β-Diketiminate caesium salts (BDICs) were synthesised, and upon the addition of Lewis donor ligands, free BDI− anions and donor-solvated Cs+ cations were observed. Notably, the liberated BDI− anions exhibited an unprecedented dynamic cisoid–transoid exchange in solution. | es_ES |
| dc.description.center | CIQSO | |
| dc.description.department | Química "Profesor José Carlos Vílchez Martín" | |
| dc.description.sponsorship | The authors acknowledge financial support from the Spanish Ministry of Science and Innovation (PID2019-108292RA-I00, EUR2020-112189), FEDER, the Andalusian Government (P20-00373), the University of Huelva (UHU- 202043), and the Spanish Research State Agency AEI for a Ramón y Cajal Research Contract (RYC-2017-21783). We thank Prof. F. J. Blas for his valuable assistance with the computational studies. Funding for open access charge: Universidad de Huelva/CBUA. | es_ES |
| dc.identifier.citation | Videa, H., & Martínez-Martínez, A. J. (2023). Revealing unbound β-diketiminate anions: structural dynamics from caesium complexes. In Dalton Transactions. Royal Society of Chemistry (RSC). https://doi.org/10.1039/d3dt01592k | es_ES |
| dc.identifier.doi | 10.1039/d3dt01592k | |
| dc.identifier.issn | 1477-9226 | |
| dc.identifier.issn | 1477-9234 (electrónico) | |
| dc.identifier.uri | https://hdl.handle.net/10272/22481 | |
| dc.language.iso | eng | es_ES |
| dc.publisher | Royal Society of Chemistry | es_ES |
| dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
| dc.rights.accessRights | open access | es_ES |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
| dc.subject.unesco | 23 Química | es_ES |
| dc.title | Revealing unbound β-diketiminate anions: structural dynamics from caesium complexes | es_ES |
| dc.type | conference output | es_ES |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | dcf621af-176c-42ae-8d9f-c288d3e1198e | |
| relation.isAuthorOfPublication.latestForDiscovery | dcf621af-176c-42ae-8d9f-c288d3e1198e |
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