Gold-catalyzed ethylene cyclopropanation

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Publication date

2019

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Química "Profesor José Carlos Vílchez Martín"

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CIQSO

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http://hdl.handle.net/10272/15934

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10.3762/bjoc.15.7

Abstract

Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr4F (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene, BAr4F = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).

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Rull, S. G., Olmos, A., & Pérez, P. J. (2019). Gold-catalyzed ethylene cyclopropanation. Beilstein Journal of Organic Chemistry, 15, 67-71. https://doi.org/10.3762/bjoc.15.7

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