Measuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophiles

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dc.contributor.authorOlmos Verge, Andrea
dc.contributor.authorGava, Riccardo
dc.contributor.authorCaballero Bevia, Ana
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2019-02-13T13:39:23Z
dc.date.available2019-02-13T13:39:23Z
dc.date.issued2018
dc.description.abstractWe report quantitative measurements of the relative reactivities of a series of C-H bonds of gaseous or liquid CnH2n+2 alkanes (n = 1-8, 29 different C-H bonds) towards insitu generated electrophiles (copper, silver, and rhodium carbenes), with methane as the reference. This strategy surpasses the drawback of previous model reactions of alkanes with strong electrophiles suffering from C-C cleavage processes, which precluded direct comparison of the relative reactivities of alkane C-H bonds.es_ES
dc.description.centerCIQSO
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"
dc.description.sponsorshipWe thank MINECO for support with Grants CTQ2014-52769-C03-01, CTQ2014-52769-C03-02, CTQ2017-82893-C2-1-R, CTQ2014-62234-EXP, CTQ2015-73693-JIN, CTQ2017-87792-R, Severo Ochoa Excellence Accreditation 2014-2018 (SEV-2013-0319), and Red Intecat (CTQ2016-81923-REDC). Junta de Andalucia is also acknowledged for Grant P12-FQM-1765. R.G. and A.O. thank MINECO for FPI and Juan delaCierva fellowships, respectively. B.N. thanks MEC for a FPU fellowship. The CNRS is thanked for support.
dc.identifier.citationOlmos, A., Gava, R., Noverges, B., Bellezza, D., Jacob, K., Besora, M., Caballero Bevia, A., Pérez Romero, P. J. (2018). Measuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophiles. Angewandte Chemie International Edition, 57(42), 13848-13852. https://doi.org/10.1002/anie.201807448es_ES
dc.identifier.doi10.1002/anie.201807448
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773 electrónico
dc.identifier.urihttp://hdl.handle.net/10272/15974
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Andalucia [P12-FQM-1765]info:eu-repo/grantAgreement/MINECO [CTQ2014-52769-C03-01, CTQ2014-52769-C03-02, CTQ2017-82893-C2-1-R, CTQ2014-62234-EXP, CTQ2015-73693-JIN, CTQ2017-87792-R]
dc.relation.publisherversionhttps://doi.org/10.1002/anie.201807448es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherAlkaneses_ES
dc.subject.otherC-H bond functionalizationes_ES
dc.subject.otherElectrophilicityes_ES
dc.subject.otherMetal carbene complexeses_ES
dc.subject.otherNucleophilicityes_ES
dc.titleMeasuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophileses_ES
dc.typejournal articlees_ES
dspace.entity.typePublication
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relation.isAuthorOfPublication.latestForDiscovery1ff94984-3f6a-4c99-a44b-3b3858c3813f

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