Recent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents

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Recent Advances in Copper-Catalyzed.pdf (2.41 MB)

Publication date

2021

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Química "Profesor José Carlos Vílchez Martín"

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Center

CIQSO

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URI

http://hdl.handle.net/10272/19697

DOI

10.1055/s-0040-1707234

Abstract

This Short Review is aimed at giving an update in the area of copper-catalyzed C–H functionalization involving nitrogen-centered radicals generated from substrates containing N–F bonds. These processes include intermolecular Csp3–H bond functionalization, remote Csp3–H bond functionalization via intramolecular hydrogen atom transfer (HAT), and Csp2–H bond functionalization, which might be of potential use in industrial applications in the future.

Keywords

Copper catalysis; C–H bond functionalization; Amination; Nitrogen–fluorine bond; Radical fluorination

Unesco Subjects

23 Química

Bibliographic citation

Muñoz Molina, J.M., Rodríguez Belderraín, T., Pérez Romero, P.J.: "Recent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents". Synthesis: Journal of Synthetic Organic Chemistry. 53(01): 51-64, (2021). http://dx.doi.org/10.1055/s-0040-1707234

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