Catalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporation

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dc.contributor.authorCarreras, Javier
dc.contributor.authorPopowski, Yanay
dc.contributor.authorCaballero Bevia, Ana
dc.contributor.authorAmir, Elizabeth
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2019-02-13T13:19:21Z
dc.date.available2019-02-13T13:19:21Z
dc.date.issued2018
dc.description.abstractThe selective catalytic functionalization of the C-H bond of azulene upon incorporation of carbene or nitrene units with metal-based catalysts is described. Ethyl diazoacetate or ArI=NTs are employed as carbene or nitrene precursors, respectively. The azulene derivatives are subsequently employed as building blocks toward more complex structures with potential use as biodegradable materials.es_ES
dc.description.centerCIQSO
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"
dc.description.sponsorshipWe thank MINECO (CTQ2017-82893-C2-1-R and Juan de la Cierva fellowship for J.C.), Junta de Andalucia for Grant P12-FQM-1765, and CHAOS COST ACTION CA-15106. We also thank Manuel A. Pulido for preliminary experiments and Francisco Molina for X-ray structure determination.
dc.identifier.citationCarreras, J., Popowski, Y., Caballero, A., Amir, E., & Pérez, P. J. (2018). Catalytic Functionalization of C–H Bonds of Azulene by Carbene/Nitrene Incorporation. The Journal of Organic Chemistry, 83(18), 11125-11132. https://doi.org/10.1021/acs.joc.8b01731es_ES
dc.identifier.doi10.1021/acs.joc.8b01731
dc.identifier.issn0022-3263
dc.identifier.issn1520-6904 electrónico
dc.identifier.urihttp://hdl.handle.net/10272/15973
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/unta de Andalucia [P12-FQM-1765]info:eu-repo/grantAgreement/MINECO [CTQ2017-82893-C2-1-R]
dc.relation.publisherversionhttps://doi.org/10.1021/acs.joc.8b01731es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherCatalytices_ES
dc.subject.otherAzulenees_ES
dc.titleCatalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporationes_ES
dc.typejournal articlees_ES
dspace.entity.typePublication
relation.isAuthorOfPublicationc0889099-8ac4-4aa5-b9b0-047f4fa34151
relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscoveryc0889099-8ac4-4aa5-b9b0-047f4fa34151

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