Rediscovering copper-based catalysts for intramolecular carbon–hydrogen bond functionalization by carbene insertion
| dc.contributor.author | Martín Gandul, Carmen | |
| dc.contributor.author | Rodríguez Belderraín, Tomás | |
| dc.contributor.author | Pérez Romero, Pedro José | |
| dc.date.accessioned | 2024-01-04T12:11:19Z | |
| dc.date.available | 2024-01-04T12:11:19Z | |
| dc.date.issued | 2009 | |
| dc.description.abstract | A series of Tp(x)Cu complexes (Tp(x) = hydrotrispyrazolylborate ligand) have been tested as catalysts for the decomposition of several diazoacetates and N,N-disubstituted diazoacetamides and the subsequent formation of lactones and lactams, respectively. The complexes containing the ligands Tp(Br3) or Tp(Ms) have provided activities and selectivities for these transformations comparable with or, in some cases, better than the well-known rhodium catalyst Rh(2)(OAc)(4) | es_ES |
| dc.description.center | CIQSO | |
| dc.description.department | Ingeniería Química, Química Física y Ciencias de los Materiales | |
| dc.description.sponsorship | We thank the MEC (Proyecto CTQ2008-00042/BQU) and the Junta de Andalucía (Proyecto P07-FQM-02794) for financial support. CM thanks the Universidad de Huelva (Plan Propio de Investigacion) for a research fellowship | es_ES |
| dc.identifier.citation | Martín, C., Belderraín, T. R., & Pérez, P. J. (2009). Rediscovering copper-based catalysts for intramolecular carbon–hydrogen bond functionalization by carbene insertion. In Organic & Biomolecular Chemistry (Vol. 7, Issue 22, p. 4777). Royal Society of Chemistry (RSC). https://doi.org/10.1039/b911589g | es_ES |
| dc.identifier.doi | 10.1039/b911589g | |
| dc.identifier.issn | 1477-0520 | |
| dc.identifier.issn | 1477-0539 (electrónico) | |
| dc.identifier.uri | https://hdl.handle.net/10272/22794 | |
| dc.language.iso | eng | es_ES |
| dc.publisher | Royal Society of Chemistry | es_ES |
| dc.relation.publisherversion | https://doi.org/10.1039/B911589G | |
| dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
| dc.rights.accessRights | open access | es_ES |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
| dc.subject.unesco | 23 Química | es_ES |
| dc.title | Rediscovering copper-based catalysts for intramolecular carbon–hydrogen bond functionalization by carbene insertion | es_ES |
| dc.type | journal article | es_ES |
| dc.type.hasVersion | AM | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 44ec727a-e9d0-466d-97eb-2c54fb56986f | |
| relation.isAuthorOfPublication | c6f8222a-d8d2-4736-baa6-4a2330bdf6b6 | |
| relation.isAuthorOfPublication.latestForDiscovery | 44ec727a-e9d0-466d-97eb-2c54fb56986f |
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