Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands

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dc.contributor.authorDelgado Rebollo, Manuela
dc.contributor.authorGarcía Morales, Cristina
dc.contributor.authorMaya, Celia
dc.contributor.authorPrieto Cárdenas, María Auxiliadora
dc.contributor.authorEchavarren, Antonio M.
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2021-03-29T10:09:14Z
dc.date.available2021-03-29T10:09:14Z
dc.date.issued2019-10
dc.description.abstractThe synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies.es_ES
dc.description.centerCIQSO
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"
dc.description.sponsorshipThe authors thank Agencia Estatal de Investigación (AEI)/FEDER (CTQ2017-82893-C2-1-R, CTQ2016- 75960-P), Red Intecat CTQ2016-81923-REDC, the AGAUR (2017 SGR 1257), and CERCA Program/Generalitat de Catalunya for financial support. M. D. R. thanks the Ministerio de Educación y Ciencia (MEC) for a FPU fellowship and C. G.-M. thanks Agencia Estatal de Investigación for a FPI predoctoral fellowship.
dc.identifier.citationDelgado-Rebollo, M., García-Morales, C., Maya, C., Prieto, A., Echavarren, A. M., & Pérez, P. J. (2019). Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands. Journal of Organometallic Chemistry, 898, 120856. https://doi.org/10.1016/j.jorganchem.2019.07.007es_ES
dc.identifier.doi10.1016/j.jorganchem.2019.07.007
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10272/19640
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/Agencia Estatal de Investigacion (AEI)/FEDER [ CTQ2017-82893-C2-1-R, CTQ2016-75960-P]
dc.relation.publisherversionhttps://doi.org/10.1016/j.jorganchem.2019.07.007es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherFluorinated N-heterocyclic carbeneses_ES
dc.subject.otherSilver carbenees_ES
dc.subject.otherGold carbenees_ES
dc.subject.otherCopper carbenees_ES
dc.subject.otherNeutral and cationic complexeses_ES
dc.subject.unesco23 Químicaes_ES
dc.titleCoinage metal complexes bearing fluorinated N-Heterocyclic carbene ligandses_ES
dc.typejournal articlees_ES
dc.type.hasVersionAM
dspace.entity.typePublication
relation.isAuthorOfPublication2f484c7e-97e4-4e36-b512-d1e3b060f474
relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscovery2f484c7e-97e4-4e36-b512-d1e3b060f474

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