Zero-valent ML2 complexes of group 10 metals supported by terphenyl phosphanes
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Abstract
Bulky terphenyl phosphane ligands PMe2Ar′ (Ar′ = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in the solid state due to the existence of Ni-Careneinteractions with the terphenyl fragment.
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Martín García, M.T., Marín Gómez, ., Jiménez Rama, R., Álvarez, E., Maya Díaz, C.M., Molina, F. y Nicasio Jaramillo, M.d.C. (2021). Zero-valent ML2complexes of Group 10 Metals Supported by Terphenyl Phosphanes. Chemical Communications, 57 (25), 3083-3086. https://doi.org/10.1039/d1cc00676b.
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