Reversible Photoswitching of Donor−Acceptor Stenhouse Adducts in Water

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dc.contributor.authorBlandón Cumbreras, Francisco G.
dc.contributor.authorJurtík, Marek
dc.contributor.authorZávodná, Aneta
dc.contributor.authorJanovský, Petr
dc.contributor.authorRouchal, Michal
dc.contributor.authorVícha, Robert
dc.contributor.authorPischel, Uwe
dc.date.accessioned2026-01-27T12:31:29Z
dc.date.available2026-01-27T12:31:29Z
dc.date.issued2025
dc.description.abstractAdamantane-substituted donor–acceptor Stenhouse adducts (DASA) form highly stable host–guest complexes with cucurbit[n]urils (n = 7, 8) in water. These assemblies show kinetic stabilization of the colored linear form and, remarkably, exhibit reversible T-type photoswitching in water. These so far elusive features for first-generation DASA reveal a strategy for their potential use in biorelevant contexts.
dc.description.centerCIQSO
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"
dc.description.sponsorshipThe authors acknowledge the funding of this work by the Spanish Ministry for Science, Innovation, and Universities (MCIU/AEI/10.13039/501100011033) and the European Regional Development Fund ERDF (grants PID2020-119992GB-I00 and PID2023-152556NB-I00 and predoctoral contract PRE2023-001520 for F.G.B.-C.) as well as the Internal Funding Agency of the Tomas Bata University in Zlín (project IGA/FT/2025/001). Funding for open access charge: Universidad de Huelva / CBUA.
dc.identifier.citationBlandón-Cumbreras, F. G., Jurtík, M., Závodná, A., Janovský, P., Rouchal, M., Vícha, R., & Pischel, U. (2025). Reversible Photoswitching of Donor–Acceptor Stenhouse Adducts in Water. Journal of the American Chemical Society, 148(1), 130–134. https://doi.org/10.1021/jacs.5c19813
dc.identifier.doi10.1021/jacs.5c19813
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126 (electrónico)
dc.identifier.urihttps://hdl.handle.net/10272/27808
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.rightsAttribution 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.otherAdducts
dc.subject.otherElectromagnetic radiation
dc.subject.otherKinetics
dc.subject.otherPhotoswitching
dc.subject.otherStabilization
dc.subject.unesco2210.22 Fotoquímica
dc.subject.unesco2210.20 Espectroscopia Molecular
dc.titleReversible Photoswitching of Donor−Acceptor Stenhouse Adducts in Water
dc.typejournal article
dc.type.hasVersionVoR
dspace.entity.typePublication
relation.isAuthorOfPublication167a3481-ecaf-42e1-b0e1-8fee1d243110
relation.isAuthorOfPublication.latestForDiscovery167a3481-ecaf-42e1-b0e1-8fee1d243110

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