Trispyrazolylborate coinage metals complexes : structural features and catalytic transformations

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Publication date

2019

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Química "Profesor José Carlos Vílchez Martín"

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CIQSO

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URI

http://hdl.handle.net/10272/16200

DOI

10.1016/j.ccr.2019.03.013

Abstract

Tris(pyrazolyl)borates (Tpx) have become one of the most broadly used polydentate anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in 1966. Herein we present a review of the main structural features of Group 11 metal complexes with Tpx ligands, as well as their catalytic properties, can be controlled by ligand steric and electronic factors.

Keywords

Group 11 metal complexes; Tris(pyrazolyl)borate; Steric hindrance; Electronic features homogeneous catalysis

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Bibliographic citation

Muñoz-Molina, J. M., Rodríguez Belderrain, T. & Pérez, P. J. (2019). Trispyrazolylborate coinage metals complexes: Structural features and catalytic transformations. Coordination Chemistry Reviews, 390, 171–189. https://doi.org/10.1016/j.ccr.2019.03.013

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