Copper(I)-Olefin Complexes:The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivity

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dc.contributor.authorMartín Gandul, Carmen
dc.contributor.authorMuñoz Molina, José María
dc.contributor.authorÁlvarez, Eleuterio
dc.contributor.authorLocati, Abel
dc.contributor.authorMaseras, Feliu
dc.contributor.authorRodríguez Belderraín, Tomás
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2024-01-04T12:07:24Z
dc.date.available2024-01-04T12:07:24Z
dc.date.issued2010
dc.description.abstractThe spectroscopic and structural characteristics and the relative reactivity of several TpMsCu(olefin) (olefin = ethylene, 1, 1-hexene, 2, allyl ethyl ether, aee, 3, cyclohexene, 4, and styrene, 5) complexes bearing the bulky hydrotris(3-mesitylpyrazolyl)borate ligand have been examined. Experimental data, including an unusual high-field chemical shift in the 1H and 13C NMR spectra, and DFT theoretical calculations support the proposal that the copper−olefin linkage is mainly sustained by σ-donation, lacking a substantial degree of π-back-donationes_ES
dc.description.centerCIQSO
dc.description.departmentIngeniería Química, Química Física y Ciencias de los Materiales
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"
dc.description.sponsorshipWe thank the MICINN (Proyecto CTQ2008−00042BQU, CTQ2008-06866-CO2-02/BQU and Consolider Ingenio 2010 grant CSD2006-0003), the Junta de Andalucía (Proyecto P07-FQM-02794), and the ICIQ Foundation for financial support. C.M. thanks the Ministerio de Educación for a research fellowshipes_ES
dc.identifier.citationMartín, C., Muñoz-Molina, J. M., Locati, A., Alvarez, E., Maseras, F., Belderrain, T. R., & Pérez, P. J. (2010). Copper(I)−Olefin Complexes: The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivity. In Organometallics (Vol. 29, Issue 16, pp. 3481–3489). American Chemical Society (ACS). https://doi.org/10.1021/om1002705es_ES
dc.identifier.doi10.1021/om1002705
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041 (electrónico)
dc.identifier.urihttps://hdl.handle.net/10272/22792
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relation.publisherversionhttps://doi.org/10.1021/om1002705
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherAdductses_ES
dc.subject.otherEthyl groupses_ES
dc.subject.otherHydrocarbonses_ES
dc.subject.otherLigandses_ES
dc.subject.otherStyreneses_ES
dc.subject.unesco23 Químicaes_ES
dc.titleCopper(I)-Olefin Complexes:The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivityes_ES
dc.typejournal articlees_ES
dc.type.hasVersionAM
dspace.entity.typePublication
relation.isAuthorOfPublication8e141a40-1260-4c0a-a95d-0ef4e63b8aad
relation.isAuthorOfPublication44ec727a-e9d0-466d-97eb-2c54fb56986f
relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscovery8e141a40-1260-4c0a-a95d-0ef4e63b8aad

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