Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation

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dc.contributor.authorRamírez Rodríguez, Manuel
dc.contributor.authorMolina González, Francisco
dc.contributor.authorDíaz Requejo, María Mar
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2025-01-10T08:33:02Z
dc.date.available2025-01-10T08:33:02Z
dc.date.issued2025-01
dc.description.abstractPhosphinoazide complexes of the composition TpBr3M-L (M = Cu, Ag, and L = 2-azido-1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole) have been synthesized and structurally characterized. Their thermal decomposition led to cyclodiphosphazenes as a result of the metal-mediated coupling of two nitrene units in a process that takes place in both a stoichiometric and catalytic manner. Experimental data have allowed proposing a mechanistic pathway for this new transformation.es_ES
dc.description.centerCIQSOes_ES
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"es_ES
dc.description.sponsorshipThe authors thank the MinistAerio de Ciencia e Innovación for Grant PID2020-113797RB-C21 and PID2023-146946NB-I00. The authors also thank Junta de Andalucía (P20-00348) and the Universidad de Huelva (P.O. Feder UHU-202016). We also thank funding for open access publication to Universidad de Huelva/CBUA. es_ES
dc.identifier.citationRodríguez, M. R., Molina, F., Díaz-Requejo, M. M., & Pérez, P. J. (2025). Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation. In Inorganic Chemistry. American Chemical Society (ACS). https://doi.org/10.1021/acs.inorgchem.4c04397es_ES
dc.identifier.doi10.1021/acs.inorgchem.4c04397
dc.identifier.issn0020-1669
dc.identifier.issn1520-510X (electrónico)
dc.identifier.urihttps://hdl.handle.net/10272/24758
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherAzideses_ES
dc.subject.otherCopperes_ES
dc.subject.otherDegradationes_ES
dc.subject.otherOrganic reactionses_ES
dc.subject.otherSilveres_ES
dc.subject.unesco23 Químicaes_ES
dc.titleCopper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generationes_ES
dc.typejournal articlees_ES
dc.type.hasVersionVoRes_ES
dspace.entity.typePublication
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relation.isAuthorOfPublication53d21d81-0d89-4eb7-b5ec-344758de6744
relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscoveryd6bc61d2-982b-4854-8502-ab8acb1d525d

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