Reversible Redox Ligand-Centered Reactivity in 2,6- Bisiminopyridine Aluminum Systems
| dc.contributor.author | Delgado Collado, Juan Manuel | |
| dc.contributor.author | Videa, Hellen | |
| dc.contributor.author | Serrano Laguna, Pablo J. | |
| dc.contributor.author | Fuentes Domínguez, María Ángeles | |
| dc.contributor.author | Álvarez, Eleuterio | |
| dc.contributor.author | Díaz Quintana, Antonio | |
| dc.contributor.author | Martínez Martínez, Antonio Jesús | |
| dc.contributor.author | Rodríguez Delgado, Antonio | |
| dc.date.accessioned | 2024-11-27T13:07:43Z | |
| dc.date.available | 2024-11-27T13:07:43Z | |
| dc.date.issued | 2024-10 | |
| dc.description.abstract | We report the synthesis of cationic 2,6-bisiminopyridine organoaluminum complexes, [(BIP)AlR2]+, as stable BArF 4 − or PF6 − salts, and their reversible single-electron reduction into well-defined paramagnetic species, [(BIP·)AlR2]. Four redox couples, [(BIP)AlR2]+/0, have been fully characterized through structural, spectroscopic, electrochemical and computational techniques | es_ES |
| dc.description.center | CIQSO | es_ES |
| dc.description.department | Química "Profesor José Carlos Vílchez Martín" | es_ES |
| dc.description.sponsorship | The authors acknowledge the financial support by the Ministerio de Ciencia e Innovación MICIN/AEI/10.13039/ 501100011033 (grants PID2021-128392NB-100 for J.C., PID2019-108292RA-I00 and PID2022-142270OB-I00 for A.J.M.-M.) and MICIN/NextGenerationEU/PRTR (CNS2022-136087 for A.J.M.-M), the Thematic Network “OASIS” RED2022-134074-T, the ERDF/EU, the Junta de Andalucía (grant P20_00104 for J.C. and P20_00373 for A.J.M.-M.) and the University of Huelva (UHU-202043 and EPIT1442023 for A.J.M.-M.). A.J.M.-M. also thanks the Spanish Research State Agency AEI for a Ramón y Cajal research (RYC-2017-21783). | es_ES |
| dc.identifier.citation | Delgado-Collado, J. M., Videa, H., Serrano-Laguna, P. J., Fuentes, M. Á., Álvarez, E., Díaz Quintana, A., Martínez-Martínez, A. J., Rodríguez-Delgado, A., & Cámpora, J. (2024). Reversible Redox Ligand-Centered Reactivity in 2,6-Bisiminopyridine Aluminum Systems. In Inorganic Chemistry (Vol. 63, Issue 41, pp. 19156–19166). American Chemical Society (ACS). https://doi.org/10.1021/acs.inorgchem.4c02664 | es_ES |
| dc.identifier.doi | 10.1021/acs.inorgchem.4c02664 | |
| dc.identifier.issn | 1520-510X (electrónico) | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.uri | https://hdl.handle.net/10272/24531 | |
| dc.language.iso | eng | es_ES |
| dc.publisher | American Chemical Society | es_ES |
| dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
| dc.rights.accessRights | open access | es_ES |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
| dc.subject.other | Active ligands | es_ES |
| dc.subject.other | Base-metal | es_ES |
| dc.subject.other | Complexes | es_ES |
| dc.subject.other | Catalysis | es_ES |
| dc.subject.other | Earth | es_ES |
| dc.subject.other | Polymerization | es_ES |
| dc.subject.other | Reduction | es_ES |
| dc.subject.other | Iron | es_ES |
| dc.subject.unesco | 23 Química | es_ES |
| dc.title | Reversible Redox Ligand-Centered Reactivity in 2,6- Bisiminopyridine Aluminum Systems | es_ES |
| dc.type | journal article | es_ES |
| dc.type.hasVersion | VoR | es_ES |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | b3438e7f-a2d4-47a2-8ca4-b515a7426bc2 | |
| relation.isAuthorOfPublication | dcf621af-176c-42ae-8d9f-c288d3e1198e | |
| relation.isAuthorOfPublication.latestForDiscovery | b3438e7f-a2d4-47a2-8ca4-b515a7426bc2 |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- delgado-collado-et-al-2024-reversible-redox.pdf
- Size:
- 3.32 MB
- Format:
- Adobe Portable Document Format
- Description:
- Versión editor