Direct, Copper-Catalyzed Oxidation of Aromatic C-H Bonds with Hydrogen Peroxide under Acid-Free Conditions

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2011-06

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Ingeniería Química, Química Física y Ciencias de los Materiales

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CIQSO

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http://hdl.handle.net/10272/11559

DOI

10.1039/c1cc12804c

Abstract

The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with TpxCu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable anthraquinones have been quantitatively obtained in the same manner

Keywords

Benzene oxidation; Copper catalysis; C-H activation

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Bibliographic citation

Conde Alcántara, A.I., Díaz Requejo, M.M., Pérez Romero, P.J.: "Direct, copper-catalyzed oxidation of aromatic C–H bonds with hydrogen peroxide under acid-free conditions". Chemical Communications. Vol. 47, págs. 8154-8156, (2011). DOI: 10.1039/C1CC12804C

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