Five-Component Self-Assembly of Cucurbituril-Based Hetero-pseudorotaxanes

Thumbnail Image

Files

Five-Component.pdf (1.18 MB)

Publication date

2017

Authors

Advisors

Department

Ingeniería Química, Química Física y Ciencias de los Materiales

Research group

Center

CIQSO

Metrics

Google Scholar

Export

Research Projects

Organizational Units

Journal Issue

URI

http://hdl.handle.net/10272/13683

DOI

10.1002/open.201600173

Abstract

[5]Pseudorotaxanes can be obtained by self-sorting using heteroditopic guests and various cucurbituril homologues as hosts. The assembly and chemically induced disassembly of the pseudorotaxanes can be monitored by measuring the fluorescence of the anthracene guest in solution. Mass spectral evidence for the supramolecular assemblies is obtained in the gas phase. The disassembly in the gas phase can be achieved by collision-induced dissociation leading to the corresponding [2]- and [3]pseudorotaxanes.

Keywords

Unesco Subjects

Bibliographic citation

Parente Caldeira Carvahlo, C.D., Domínguez Hidalgo, Z., Domínguez Linares, C., El- Sheshtawy, H.S., Da Silva, J.P., Fernández Arteaga, J., Pischel, U.: "Five-Component Self-Assembly of Cucurbituril-Based Hetero-pseudorotaxanes". ChemistryOpen. Vol. 6, n. 2, págs. 288–294, (2017). DOI: 10.1002/open.201600173

Collections

Artículos
Atribución-NoComercial-SinDerivadas 3.0 España
The license for this item is described as Atribución-NoComercial-SinDerivadas 3.0 España