Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T

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2008

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Química "Profesor José Carlos Vílchez Martín"

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Center

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https://hdl.handle.net/10272/22780

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10.1039/B813469C

Abstract

The complex [Tpm*,BrCu(NCMe)]BF4 (Tpm*,Br = HC(3,5-Me2-4-Br-pyrazolyl)3) catalyses the aziridination of alkenes and the amidation of cyclic ethers with chloramine-T as the nitrene source and the ionic liquid [bmim]PF6 as the reaction medium (bmim = 1-n-butyl-3-methylimidazolium). High conversions have been obtained over several cycles of catalyst recovery and reuse.

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23 Química

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Cano, I., Nicasio, M. C., & Pérez, P. J. (2009). Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T. In Dalton Trans. (Issue 4, pp. 730–734). Royal Society of Chemistry (RSC). https://doi.org/10.1039/b813469c

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