The TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag)

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dc.contributor.authorDíaz Requejo, María Mar
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2021-03-29T11:11:07Z
dc.date.available2021-03-29T11:11:07Z
dc.date.issued2020-03
dc.description.abstractA comparison between three TpxM‐catalyzed (Tpx = scorpionate ligand; M = Cu, Ag) reactions leading to the functionalization of non‐activated, alkane Csp3–H bonds by carbene, nitrene or oxo insertion is presented. Analogies and differences in these transformations are discussed, including main reactive intermediates, selectivity trends and mechanistic interpretations.es_ES
dc.description.centerCIQSO
dc.description.departmentQuímica "Profesor José Carlos Vílchez Martín"
dc.description.sponsorshipSupport for this work was provided by the MINECO (CTQ2017-82893-C2-1-R).
dc.identifier.citationDíaz‐Requejo, M. M., & Pérez, P. J. (2020). The Tp x M Core in C sp 3 –H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tp x = Scorpionate Ligand; M = Cu, Ag). European Journal of Inorganic Chemistry, 2020(11–12), 879–885. https://doi.org/10.1002/ejic.201901168es_ES
dc.identifier.doi10.1002/ejic.201901168
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682 (electrónico)
dc.identifier.urihttp://hdl.handle.net/10272/19643
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO [CTQ2017-82893-C2-1-R]
dc.relation.publisherversionhttps://doi.org/10.1002/ejic.201901168es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherTrispyrazolylborate ligandses_ES
dc.subject.otherCopper and silver catalystses_ES
dc.subject.otherCarbene nitrene oxo• C-H functionalizationes_ES
dc.subject.otherAlkane catalysises_ES
dc.subject.unesco23 Químicaes_ES
dc.titleThe TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag)es_ES
dc.typejournal articlees_ES
dc.type.hasVersionAM
dspace.entity.typePublication
relation.isAuthorOfPublication53d21d81-0d89-4eb7-b5ec-344758de6744
relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscovery53d21d81-0d89-4eb7-b5ec-344758de6744

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