The TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag)

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Publication date

2020-03

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Química "Profesor José Carlos Vílchez Martín"

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CIQSO

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http://hdl.handle.net/10272/19643

DOI

10.1002/ejic.201901168

Abstract

A comparison between three TpxM‐catalyzed (Tpx = scorpionate ligand; M = Cu, Ag) reactions leading to the functionalization of non‐activated, alkane Csp3–H bonds by carbene, nitrene or oxo insertion is presented. Analogies and differences in these transformations are discussed, including main reactive intermediates, selectivity trends and mechanistic interpretations.

Keywords

Trispyrazolylborate ligands; Copper and silver catalysts; Carbene nitrene oxo• C-H functionalization; Alkane catalysis

Unesco Subjects

23 Química

Bibliographic citation

Díaz‐Requejo, M. M., & Pérez, P. J. (2020). The Tp x M Core in C sp 3 –H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tp x = Scorpionate Ligand; M = Cu, Ag). European Journal of Inorganic Chemistry, 2020(11–12), 879–885. https://doi.org/10.1002/ejic.201901168

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