Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts

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dc.contributor.authorRivilla de la Cruz, Iván
dc.contributor.authorGómez Emeterio, Bella Pilar
dc.contributor.authorRomero Fructos-Vázquez, Manuel
dc.contributor.authorDíaz Requejo, María Mar
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2016-01-11T10:06:25Z
dc.date.available2016-01-11T10:06:25Z
dc.date.issued2011
dc.description.abstractThe direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developeden_US
dc.description.centerCIQSO
dc.description.departmentIngeniería Química, Química Física y Ciencias de los Materiales
dc.description.sponsorshipDGI (CTQ2008-00042BQU and Consolider Ingenio 2010, Grant CSD2006-0003) and Junta de Andalucía (P07-FQM-02870)
dc.identifier.citationRivilla de la Cruz, I., Gómez Emeterio, B.P., Romero Fructos-Vazquez, M., Díaz Requejo, M.M., Pérez Romero, P.J.: "Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts". Organometallics. Vol. 30 (10), págs. 2855–2860, (2011). DOI: 10.1021/om200206m
dc.identifier.doi10.1021/om200206m
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041 (electrónico)
dc.identifier.urihttp://hdl.handle.net/10272/11556
dc.language.isoengen_US
dc.publisherAmerican Chemical Society
dc.relation.publisherversionhttp://dx.doi.org/10.1021/om200206m
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accessen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherGold catalysis
dc.subject.otherCarbene transfer
dc.subject.otherC-H functionalization
dc.subject.otherNHC ligands
dc.subject.otherDiazo compounds
dc.titleExclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalystsen_US
dc.typejournal articleen_US
dspace.entity.typePublication
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relation.isAuthorOfPublication4c3de728-2a65-41a6-ad65-81e751665290
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relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscovery6dfeb729-27ac-40f4-8240-892789c7f603

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