Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides
| dc.contributor.author | Muñoz Molina, José María | |
| dc.contributor.author | Pérez Romero, Pedro José | |
| dc.date.accessioned | 2019-10-03T08:09:18Z | |
| dc.date.available | 2019-10-03T08:09:18Z | |
| dc.date.issued | 2019-05-27 | |
| dc.description.abstract | The complex [Cp*RuCl(PPh3)2] displays a high catalytic activity for the Heck-type alkenylation of alkyl bromides, in the first example using this metal under thermal conditions. The coupling reaction proceeds efficiently with a variety of functionalized tertiary, secondary, and primary alkyl bromides. The presence of Hünig’s base has been revealed crucial for this transformation. Preliminary mechanistic studies support the participation of alkyl radicals in the reaction. | es_ES |
| dc.description.center | CIQSO | |
| dc.description.department | Química "Profesor José Carlos Vílchez Martín" | |
| dc.description.sponsorship | We thank MINECO for a grant (CTQ2017-82893-C2-1-R). We also thank Francisco Molina for X-ray structure determination | |
| dc.identifier.citation | Muñoz Molina, J.M., Pérez Romero, P.J.: "Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides". Journal of Organic Chemistry. Vol. 84, 12, (2019). https://doi.org/10.1021/acs.joc.9b00898 | es_ES |
| dc.identifier.doi | 10.1021/acs.joc.9b00898 | |
| dc.identifier.issn | 0022-3263 | |
| dc.identifier.issn | 1520-6904 (electrónico) | |
| dc.identifier.uri | http://hdl.handle.net/10272/16747 | |
| dc.language.iso | eng | es_ES |
| dc.publisher | American Chemical Society | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/Spanish Ministry of Economy & Competitiveness [CTQ2017-82893-C2-1-R] | |
| dc.relation.publisherversion | https://doi.org/10.1021/acs.joc.9b00898 | es_ES |
| dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
| dc.rights.accessRights | open access | es_ES |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
| dc.subject.other | Ruthenium catalysis | es_ES |
| dc.subject.other | Alkenylation | es_ES |
| dc.subject.other | Cross-coupling | es_ES |
| dc.subject.other | Single electron transfer | es_ES |
| dc.subject.other | Homogeneous catalysis | es_ES |
| dc.title | Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides | es_ES |
| dc.type | journal article | es_ES |
| dc.type.hasVersion | AM | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 8e141a40-1260-4c0a-a95d-0ef4e63b8aad | |
| relation.isAuthorOfPublication | c6f8222a-d8d2-4736-baa6-4a2330bdf6b6 | |
| relation.isAuthorOfPublication.latestForDiscovery | 8e141a40-1260-4c0a-a95d-0ef4e63b8aad |
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