Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand

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dc.contributor.authorFuentes Domínguez, María Ángeles
dc.contributor.authorRodríguez Castillo, María
dc.contributor.authorMonge, Miguel
dc.contributor.authorOlmos, M. Elena
dc.contributor.authorLópez de Luzuriaga, José M.
dc.contributor.authorCaballero Bevia, Ana
dc.contributor.authorPérez Romero, Pedro José
dc.date.accessioned2016-01-11T08:50:26Z
dc.date.available2016-01-11T08:50:26Z
dc.date.issued2011
dc.description.abstractThe complexes [Au2M2(C6F5)4(NCMe)2]n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the proposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)2 unit acting as a spectator ligand in both cases.en_US
dc.description.centerCIQSO
dc.description.departmentIngeniería Química, Química Física y Ciencias de los Materiales
dc.description.sponsorshipDGI for funding (CTQ2008-00042/BQU and CTQ2010-20500-C02-02)
dc.identifier.citationFuentes, M.A., Rodríguez Castillo, M., Monge, M., Olmos, M. Elena, López de Luzuriaga, J.M., Caballero Bevia, A., Pérez Romero, P.J.: "Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand". Inorganica Chimica Acta. Vol. 369, n. 1, págs. 146-149, (2011). DOI: 10.1016/j.ica.2011.01.012
dc.identifier.doi10.1016/j.ica.2011.01.012
dc.identifier.issn0020-1693
dc.identifier.urihttp://hdl.handle.net/10272/11555
dc.language.isoengen_US
dc.publisherElsevier
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.ica.2011.01.012
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accessen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.otherC–H functionalization
dc.subject.otherDiazocompounds
dc.subject.otherCarbenes
dc.subject.otherCoinage metals
dc.titleIntermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a liganden_US
dc.typejournal articleen_US
dspace.entity.typePublication
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relation.isAuthorOfPublicationc0889099-8ac4-4aa5-b9b0-047f4fa34151
relation.isAuthorOfPublicationc6f8222a-d8d2-4736-baa6-4a2330bdf6b6
relation.isAuthorOfPublication.latestForDiscoveryb3438e7f-a2d4-47a2-8ca4-b515a7426bc2

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