Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand
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Abstract
The complexes [Au2M2(C6F5)4(NCMe)2]n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization
of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene
source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the
proposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)2 unit acting as a spectator
ligand in both cases.
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Bibliographic citation
Fuentes, M.A., Rodríguez Castillo, M., Monge, M., Olmos, M. Elena, López de Luzuriaga, J.M., Caballero Bevia, A., Pérez Romero, P.J.: "Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand". Inorganica Chimica Acta. Vol. 369, n. 1, págs. 146-149, (2011). DOI: 10.1016/j.ica.2011.01.012
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